Energy from Biomass needs highly efficient small-scale energy systems in order to achieve cost effective solutions for decentralized generation. Especially in Mediterranean and southern areas, and for applications without adequate heat consumers highest efficiencies are needed due to the fact that no revenues for heat may be achieved. Thus fuel cells are an attractive option for these decentralized generation from biomass and agricultural residues.
Due to their robustness SOFC fuel cells are applicable above all other concepts for the use of gaseous fuels from biomass. They operate with exhaust gas temperatures between 800°C and 1000°C and are able to convert not only hydrogen but also carbon monoxide and even hydrocarbons.
Other fuel cell concepts, for example the PEM fuel cells, make extremely high demands against the purity of the gaseous fuels. Carbon monoxide, hydrocarbons, dust and tars must be separated restrictively before.
High temperature fuel cells like the SOFC and the MCFC are therefore the
most promising options for upcoming fuel cell systems with integrated gasification. But even if the fuel gas matches the strict requirements of SOFC membranes the main challenge of the conversion of biogeneous fuel gas is to achieve the required efficiency of the fuel cell system. Common biomass fuel cell systems with realistic boundary conditions will hardly reach efficiencies above 30% due to:

• the low hydrogen and methane content of biogenious fuel gases, which reduces the fuel cell efficiency

• the physical limitation of the cold gas efficiency of any gasification system

 

Thus the system performance and the thermal integration of the gasification process is of particular importance.
The most common gasifiers work autothermal. The main disadvantage of autothermal gasifiers is the high auxiliaries service and the low heating value of the produced gas. If the gasifier works with air the nitrogen content dilutes the product gas and the product gas contains only about 70% of the total energy in chemically bonded form. Due to high mass flow rates and temperatures around 800°C more than 30 percent of the energy input leaves the gasifier as sensible heat. The main advantage of allothermal gasifiers (‘indirect gasification’) is that they provide much higher heating values. The sensitive heat in the product gas is reduced to a minimum because no nitrogen dilutes the gas output. The main disadvantage of allothermal gasifiers is that a part of the produced gas has to be used in an external furnace to provide the heat for the endothermal reforming of the biomass.
[Text: Dr. J. Karl, TUM]